So is the header leaking at the head or collector? The best way to check at the head is using a stethoscope but most do not have one. If there are leaks up at the head than you can spray the flange and gasket with copper coat. It comes in a small spray paint can and is available at any auto parts store. As far as the collector goes the coller ring must be centered and seat into the bevel of the flange. Are the header and cat flange smashed together or is there a gap between the 2?
Nick
Nick