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They tend to become inefficient over time, that's all. Yes, a bad running engine can ruin a converter, but sometimes they just go bad on their own. I've replaced both of my front converters on my 06 Pathfinder. Check with Rockauto.com; I believe Walker makes C.A.R.B. certified replacement catalytic converters that are a lot less expensive than genuine Nissan parts.
 

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The C.A.R.B. certified aftermarket converters will come with a sticker that states they are such to be installed in the engine compartment. Looking at Walker's catalog, it doesn't look like they make C.A.R.B. certified converters for the 2005-11 Frontier V6. Your only option might be genuine Nissan or emission-certified, used converters.
 
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